I could potentially just exclude this small group from the analysis.
I think the thing to think about is what you said in #1: "I would like help to generate a variable, say level of education "educ" for the male partner and female partner in a union (either married or de facto). " Your question seems to be specifically about couples with one male and one female partner. If that was accurate, then excluding the same-sex couples from this analysis is the way to go.
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